Bis(2,2′-bipyridyl-κ2 N,N′)bis­(dicyanamido-κN)manganese(II)

نویسندگان

  • Haixia Wang
  • Shaohong Wang
  • Yuehe Lang
چکیده

In title complex, [Mn(C(2)N(3))(2)(C(10)H(8)N(2))(2)], the Mn(II) ion is coordinated in a slightly distorted octa-hedral geometry by six N atoms. Four of the N atoms are from two chelating bipyridine ligands and two are from a pair of cis-coordinated dicyanamide ligands. The dihedral angle formed by the mean planes of the bipyridine rings is 85.93 (14)°. The central N atom of one of the dicyanamide ligands was refined as disordered over two sites with equal occupancies.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Bis(dicyanamido-κN 1)bis­[2-(2-hydroxy­ethyl)pyridine-κ2 N,O]nickel(II)

In the title complex, [Ni{N(CN)(2)}(2)(C(7)H(9)NO)(2)], the Ni(II) ion (site symmetry ) adopts a distorted trans-NiO(2)N(4) octa-hedral geometry. In the crystal, inter-molecular O-H⋯N hydrogen bonds link the mol-ecules, forming a chain along the c axis.

متن کامل

Poly[[bis­(μ-4,4′-bipyridyl-κ2 N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]

In the title compound, {[Mn(NCS)(2)(C(10)H(8)N(2))(2)]·2C(4)H(10)O}(n), the Mn(II) ion is coordinated by four N-bonded 4,4'-bipyridine (bipy) ligands and two N-bonded thio-cyanate anions in a distorted octa-hedral coordination geometry. The asymmetric unit consists of one Mn(II) ion and two bipy ligands each located on a twofold rotation axis, as well as one thio-cyanate anion and one diethyl e...

متن کامل

Bis(μ2-benzoato-κ2 O:O′)bis­[(benzoato-κ2 O,O′)bis(4,4′-bi­pyridine-κN)cobalt(II)]–benzoic acid (1/6)

In the title compound, [Co2(C7H5O2)4(C10H8N2)4]·6C6H5COOH, the centrosymmetric cobalt dimer co-crystallizes with six mol-ecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4'-bipyridyl ligands are 25.2 (2) and 22.8 (2)°. ...

متن کامل

Bis(2,2′-bipyridine-κ2 N,N′)bis­(dicyan­amido-κN 1)cadmium

In the title compound, [Cd(C(2)N(3))(2)(C(10)H(8)N(2))(2)], the Cd(II) ion is coordinated in a distorted octa-hedral environment by four N atoms from two chelating 2,2'-bipyridine ligands and two N atoms from two monodentate dicyanamide ligands. The dihedral angle between the mean planes of the two bipyridine ligands is 87.67 (6)°.

متن کامل

Bis(acetato-κ2 O,O′)[2,6-bis­(1H-pyrazol-3-yl-κN 2)pyridine-κN]manganese(II)

In the title complex, [Mn(CH(3)CO(2))(2)(C(11)H(9)N(5))], the Mn(II) atom is coordinated by the pyridine N atom and two pyrazole N atoms from a 2,6-bis-(pyrazol-3-yl)pyridine ligand and four O atoms from two bidentate acetate ligands. The complex mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds into a chain along [010]. π-π inter-actions between the pyridine rings and between the p...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012